Ab initio calculations of the relative energetics of the π- and σ-states of the succinimidyl radical including geometry optimization and electron correlation result in the following relative energies (in kJ mol–1): Sπ, 0.0, Sσ(N), 21.5; Sσ(O), 168.9.
M. J. Field, I. H. Hillier, S. A. Pope and M. F. Guest, J. Chem. Soc., Chem. Commun., 1985, 219 DOI: 10.1039/C39850000219
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