X-Ray crystal structure analysis of the nickel(II) 16-membered dioxopenta-amine macrocyclic complex (1) reveals that the constrained ligand configuration and the possible electron-sink properties of the deprotonated amide donors could be favourable for its interaction with O2.
Y. Kushi, R. Machida and E. Kimura, J. Chem. Soc., Chem. Commun., 1985, 216 DOI: 10.1039/C39850000216
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