Issue 4, 1985

Synthesis of an unusual, high nuclearity osmium–platinum cluster: X-ray analysis of [Os6Pt2(CO)16(C8H12)2](C8H12= cyclo-octa-1,5-diene)

Abstract

Reaction of [Os6(CO)18–n(NCMe)n], n= 1 or 2, with [Pt(C8H12)2](C8H12= cyclo-octa-1,5-diene) results in formation [Os6Pt2(CO)17(C8H12)2](1) and [Os6Pt2(CO)16(C8H12)2](2), respectively, and (2) has been shown by X-ray analysis to possess the unusual metal core geometry of two edge-fused Os tetrahedral, one of which is Pt-bicapped.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 197-198

Synthesis of an unusual, high nuclearity osmium–platinum cluster: X-ray analysis of [Os6Pt2(CO)16(C8H12)2](C8H12= cyclo-octa-1,5-diene)

C. Couture and D. H. Farrar, J. Chem. Soc., Chem. Commun., 1985, 197 DOI: 10.1039/C39850000197

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