SCHEDULED MAINTENANCE
A ‘basket-handle’ iron-porphyrin bearing L-phenylalanine residues has been prepared and found to catalyse the epoxidation of p-chlorostyrene with a 50% excess of the (R)-epoxide, whereas ‘picket’ iron-porphyrins bearing the same amino acid have led to a 10–20% excess of the (S)-epoxide.
D. Mansuy, P. Battioni, J.-P. Renaud and P. Guerin, J. Chem. Soc., Chem. Commun., 1985, 155 DOI: 10.1039/C39850000155
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