Issue 11, 1984

A study of the ‘head’ addition of benzoyloxyl radicals to vinyl acetate

Abstract

The radicals formed by the addition of the benzoyloxyl radical to vinyl acetate have been studied employing 2-methyl-2-nitrosopropane and 2,4,6-tri-t-butylnitrosobenzene as spin traps. The resulting e.s.r. spectrum of the radicals obtained using the latter spin trap indicates that a significant proportion (i.e. 3:10) of the benzoyloxyl radicals add to the substituted carbon atom of the C[double bond, length as m-dash]C bond (‘head’ addition).

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1984, 1823-1826

A study of the ‘head’ addition of benzoyloxyl radicals to vinyl acetate

J. Lane and B. J. Tabner, J. Chem. Soc., Perkin Trans. 2, 1984, 1823 DOI: 10.1039/P29840001823

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