The Helα photoelectron spectra of the title compound and four methyl derivatives are measured and analysed in terms of simple Hückel-type arguments and the results of semiempirical EWMO and HAM/3 calculations. The presence of strong through-bond interaction leading to a highly destabilized totally symmetric nitrogen ‘non-bonding’ orbital is confirmed.
R. Gleiter, J. Spanget-Larsen and W. L.F. Armarego, J. Chem. Soc., Perkin Trans. 2, 1984, 1517 DOI: 10.1039/P29840001517
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