The 13C n.m.r. spectra of a few carbonyl donors have been recorded in the presence of Li+, Na+, and Mg2+. The 13C resonances of carbonyl and other groups shift downfield on interaction with the ions. The solvation numbers of Na+ with acetone and cyclohexanone have been determined from 23Na n.m.r. spectra.
A. S. N. Murthy and A. P. Bhardwaj, J. Chem. Soc., Perkin Trans. 2, 1984, 727 DOI: 10.1039/P29840000727
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