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Kinetic and stereochemical evidence has been obtained from the dehydromethoxylation of 2-halogeno-3-methoxy-1,3-diphenylpropan-2-ones with isopropoxide in isopropyl alcohol that is consistent with an E1cB reversible mechanism. The influence of the halogen both on the deprotonation rate and upon the methoxy-group expulsion has been evaluated.
M. C. Cabaleiro and R. O. Garay, J. Chem. Soc., Perkin Trans. 2, 1984, 179 DOI: 10.1039/P29840000179
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