N 1 - and N8-Substituted spermidine (1) conjugates formed with different oxygenated cinnamic acids occur in many higher plants and also in some micro-organisms. A short and efficient synthetic route to such compounds (14)–(17), (21), and (22) is described by way of the suitably protected spermidine derivative (2) which undergoes selective deprotection and monoacylation.
R. Sundaramoorthi, J. Fourrey and B. C. Das, J. Chem. Soc., Perkin Trans. 1, 1984, 2759 DOI: 10.1039/P19840002759
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