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Issue 0, 1984
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The structures of pseudoanisatin and its novel base-catalysed rearrangement product

Abstract

The oxidation product of pseudoanisatin (4), the structure of which was known from an X-ray crystallographic analysis, has been assigned as (7) on the basis of chemical and spectral evidence. A base-catalysed rearrangement product of pseudoanisatin, assigned structure (8) from an X-ray crystallographic analysis, is formed, it is concluded, via a novel stereoselective reaction which involves steric inversions at C-3 and C-4.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1984, 2511-2515
Article type
Paper

The structures of pseudoanisatin and its novel base-catalysed rearrangement product

I. Kouno, H. Irie and N. Kawano, J. Chem. Soc., Perkin Trans. 1, 1984, 2511
DOI: 10.1039/P19840002511

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