SCHEDULED MAINTENANCE
Benz[a]anthracene 1,2-oxide (1,2-epoxy-1,2-dihydrobenz[a]anthracene), a minor metabolite of benz[a]anthracene in hepatic systems, has been synthesized both from racemic precursors and from separated diastereoisomeric bromohydrin esters whose absolute stereochemistry has been determined by n.m.r. methods. The benz[a]anthracene 1,2-oxide obtained was racemic as previously predicted from PMO calculations.
D. R. Boyd and N. D. Sharma, J. Chem. Soc., Perkin Trans. 1, 1984, 839 DOI: 10.1039/P19840000839
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