The direct synthesis of three new 2-oxidodiaryliodonium zwitterions from phenols and aryliodine(III) bistrifluoroacetate and their reaction with nucleophiles and electrophiles are reported. Especially noteworthy is the reactivity of 2-methoxy-3,5-dinitrophenyl(phenyl)iodonium tetrafluoroborate (15) which is hydrolysed by water and solvolysed by alcohols at room temperature.
S. Spyroudis and A. Varvoglis, J. Chem. Soc., Perkin Trans. 1, 1984, 135 DOI: 10.1039/P19840000135
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