Issue 11, 1984

Synthesis and crystal structure of [{W(SEt)O(PMe2Ph)}2(µ-S)(µ-SEt)2]

Abstract

Reaction of cis-[W(N2)2(PMe2Ph)4] with EtSH in air leads to the formation of the diamagnetic complex [{W(SEt)O(PMe2Ph)}2(µ-S)(µ-SEt)2] which is shown by X-ray analysis to have a confacial bioctahedral structure with cis-oxo-ligands.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1984, 2585-2587

Synthesis and crystal structure of [{W(SEt)O(PMe2Ph)}2(µ-S)(µ-SEt)2]

D. C. Povey and R. L. Richards, J. Chem. Soc., Dalton Trans., 1984, 2585 DOI: 10.1039/DT9840002585

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