Dodecacarbonyltriosmiun reacts with polystyrene cross-linked poly(4-vinylpyridine) to give polymer-anchored cluster derivatives. The solution 1H n.m.r. spectrum of the polymer shows that the major species corresponds to one of the isomers of [Os3(CO)9(NC5H4)(py)](py = pyridine).
S. Bhaduri, H. Khwaja and B. A. Narayanan, J. Chem. Soc., Dalton Trans., 1984, 2327 DOI: 10.1039/DT9840002327
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