The preparation, crystal structure, and electrical conduction properties of Rb[Pt{S2C2(CN)2}2]·2H2O are described. The planar anions are arranged in a dimeric eclipsed configuration to form a columnar stacked structure. The room-temperature conductivity in the platinum atom chain direction is 2.5 ×10–5Ω–1 cm–1 and the compound behaves as a semiconductor.
M. M. Ahmad, D. J. Turner, A. E. Underhill, A. Kobayashi, Y. Sasaki and H. Kobayashi, J. Chem. Soc., Dalton Trans., 1984, 1759 DOI: 10.1039/DT9840001759
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