The redox behaviour of trans-[NBun4][Au(CN)2X2](X = Cl, Br, or I) and [NBun4][Au(CN)2] have been investigated in acetonitrile solution. The effect of σ and π donor halides and π acceptor cyanide on the redox behaviour have also been studied. Intermediates are observed in the redox reactions of these systems.
J. Hacaloğlu, N. K. Tunali and U. Akbulut, J. Chem. Soc., Dalton Trans., 1984, 715 DOI: 10.1039/DT9840000715
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