Issue 3, 1984
From the journal:

Journal of the Chemical Society, Dalton Transactions

Notes. Kinetics of silver(II) oxidation of metal cations

Patrizia Arselli,   Claudio Baiocchi,   Edoardo Mentasti  and  John S. Coe  

Abstract

The oxidation of Fe2+, Mn2+, Co2+, Ce3+, and VO2+ by silver(II) has been investigated with a stopped-flow technique. The reactions of Mn2+ and Ce3+ occur through two competitive paths involving Ag2+ and AgOH+. For the other cations a single pathway with Ag2+ as oxidant has been observed. An inner-sphere interaction mechanism is proposed and discussed with reference to the electron configuration of the reductant and to the behaviour predicted by the Marcus cross relation.

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Article information

DOI
https://doi.org/10.1039/DT9840000475
Article type
Paper

J. Chem. Soc., Dalton Trans., 1984, 475-477

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Notes. Kinetics of silver(II) oxidation of metal cations

P. Arselli, C. Baiocchi, E. Mentasti and J. S. Coe, J. Chem. Soc., Dalton Trans., 1984, 475 DOI: 10.1039/DT9840000475

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