Issue 8, 1984

Experimental and theoretical studies on the charge stripping from CH3X+ and CH2XH+˙ ions (X = F, Cl, Br, I, OH, SH, or NH2)

Abstract

Charge stripping from aither Ch2XH+˙ or CH3X+˙ cation radicals (X = F, Cl, Br, I, OH, SH, or NH2) results in the formation of ovservable dications; a comparison of experimentally derived Qmin data for the process m+→m2+ with the computed vertical ionization energies, I.E.v suggests that whereas electron removal from CH2XH+· results directly in the formation of the corresponding dications, i.e. CH2XH2+, charge stripping from CH3Z+˙ does not lead to stable CH3X2+ species, but instead rearrangement (perhaps from a Rydberg state of CH3X+˙) is likely to take place to give CH2XH2+ ions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 504-506

Experimental and theoretical studies on the charge stripping from CH3X+ and CH2XH+˙ ions (X = F, Cl, Br, I, OH, SH, or NH2)

F. Maquin, D. Stahl, A. Sawaryn, P. V. R. Schleyer, W. Koch, G. Frenking and H. Schwarz, J. Chem. Soc., Chem. Commun., 1984, 504 DOI: 10.1039/C39840000504

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements