The effective concentration of intramolecular hydride transfer in a rigid hydroxy-ketone is 6.5 × 106M compared with amodel intermolecular process; this contrasts with low values normally observed for proton transfer and is compatible with a tighter transition state for hydride transfer.
A. M. Davis, M. I. Page, S. C. Mason and I. Watt, J. Chem. Soc., Chem. Commun., 1984, 1671 DOI: 10.1039/C39840001671
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