Issue 24, 1984

The key role of water in solid–liquid phase transfer-catalysed substitution reactions

Abstract

Traces of water are shown to be essential for substitution reactons catalysed by quaternary ammonium salts; in chloride–formate exchange maximum rate is observed with 0.2% water content of the formate salt, and addition of dehydrating agents reduces the maximum rate by 50%.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1652-1654

The key role of water in solid–liquid phase transfer-catalysed substitution reactions

H. A. Zahalka and Y. Sasson, J. Chem. Soc., Chem. Commun., 1984, 1652 DOI: 10.1039/C39840001652

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