The silver-mediated cyclisation of secondary allenic alcohols is streoselective giving predominantly cis-2,6-disubstituted tetrahydropyrans; this methodology has been applied to the synthesis of the civet constituent (4).
T. Gallagher, J. Chem. Soc., Chem. Commun., 1984, 1554 DOI: 10.1039/C39840001554
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