Thermolyses of β-aminoacetylenes with a terminal acetylenic bond and of β-amino-olefins afford retro-ene reactions in which nitrogen acts as the hydrogen donor, whereas alkyl subsitution on the terminus of the acetylenic bond leads to a novel, facile cyclization to a 2-alkylidenepyrrolidine.
A. Viola and J. S. Locke, J. Chem. Soc., Chem. Commun., 1984, 1429 DOI: 10.1039/C39840001429
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