Issue 21, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Syntheses and crystal structures of ‘encapsulated’ guanidinium complexes of 27-membered macrocyclic ligands

Catherina J. van Staveren,   Herman J. den Hertog, Jr.,   David N. Reinhoudt,   Jos W. H. M. Uiterwijk,   Laminus Kruise  and  Sybolt Harkema  

Abstract

X-Ray structures of complexes of 2,6-pyrido-27-crown-9 and 1,3-xylyl-27-crown-8 with guanidinium perchlorate show a complementary hydrogen bonding relationship between host and guest; in the former complex the pyridyl nitrogen is used preferentially as a hydrogen binding site; the structures found are compared with those of the protonated 27-membered macrocycle and with 2,6-pyrido-24-crown-8.

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Article information

DOI
https://doi.org/10.1039/C39840001409
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1409-1411

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Syntheses and crystal structures of ‘encapsulated’ guanidinium complexes of 27-membered macrocyclic ligands

C. J. van Staveren, H. J. den Hertog, D. N. Reinhoudt, J. W. H. M. Uiterwijk, L. Kruise and S. Harkema, J. Chem. Soc., Chem. Commun., 1984, 1409 DOI: 10.1039/C39840001409

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