Issue 21, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Trimethylphosphine–tungsten chemistry: hydrido, silyl, fluoro, hydroxy, and aquo derivatives: crystal structure of [W(PMe3)4H2(OH2)F]F

Malcolm L. H. Green,   Gerard Parkin,   Chen Mingqin  and  Keith Prout  

Abstract

The compounds W(PMe3)4H2X2(X = H, F, SiH3), [W(PMe3)4H2(OH)2]2+[BF4–]2, and [W(PMe3)4H2(OH2)F]F, whose crystal structure has been determined, are described; W(PMe3)4(η2-CH2PMe2)H reacts with ethylene giving inter alia W(η-C4H6)2(PMe3)2.

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Article information

DOI
https://doi.org/10.1039/C39840001400
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1400-1402

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Trimethylphosphine–tungsten chemistry: hydrido, silyl, fluoro, hydroxy, and aquo derivatives: crystal structure of [W(PMe3)4H2(OH2)F]F

M. L. H. Green, G. Parkin, C. Mingqin and K. Prout, J. Chem. Soc., Chem. Commun., 1984, 1400 DOI: 10.1039/C39840001400

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