Issue 19, 1984

The X-ray crystal structure of trans-bis(sulphur dioxide)tetrakis(triphenylphosphineoxide)manganese(II) di-iodide, a compound which undergoes demi-reversible binding of sulphur dioxide: the first crystallographically characterised example of O-bonded sulphur dioxide in a transition metal complex

Abstract

The X-ray crystal structure of the complex trans-[Mn(OPPh3)4(SO2)2]I2 shows it to contain O-bonded Sulphur dioxide groups; one of these can be lost to form Mn(OPPh3)4(SO2)I2, and the reaction is reversible.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1283-1284

The X-ray crystal structure of trans-bis(sulphur dioxide)tetrakis(triphenylphosphineoxide)manganese(II) di-iodide, a compound which undergoes demi-reversible binding of sulphur dioxide: the first crystallographically characterised example of O-bonded sulphur dioxide in a transition metal complex

G. A. Gott, J. Fawcett, C. A. McAuliffe and D. R. Russell, J. Chem. Soc., Chem. Commun., 1984, 1283 DOI: 10.1039/C39840001283

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