Issue 18, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Nitrogen-15 n.m.r. evidence for rapid intramolecular interconversion of linear and bent nitrosyl ligands in [RuCl(NO)2(PPh3)2](BF4), with observation of a ntrogen-14,15 equilibrium isotope effect

Joan Mason,   D. Michael P. Mingos,   Darren Sherman  and  Robert W. M. Wardle  

Abstract

15 N N.m.r. evivdence is presented for rapid intramolecular interconversion of bent and linear nitrosyl ligands in [RuCl(NO)2(PPh3)2](BF4) in solution, from an 14,15N equilibrium isotope effect observed with semi-15N-enrichment; also for the contribution of more than one co-ordination geometry to the fluxionality, and for slow intermolecular nitrosyl exchange.

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Article information

DOI
https://doi.org/10.1039/C39840001223
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1223-1225

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Nitrogen-15 n.m.r. evidence for rapid intramolecular interconversion of linear and bent nitrosyl ligands in [RuCl(NO)2(PPh3)2](BF4), with observation of a ntrogen-14,15 equilibrium isotope effect

J. Mason, D. M. P. Mingos, D. Sherman and R. W. M. Wardle, J. Chem. Soc., Chem. Commun., 1984, 1223 DOI: 10.1039/C39840001223

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