Preparations of the enzyme isopenicillin N synthetase from Cephalosporium acremonium CO 728 convert the modified tripeptide substrate δ-(L-α-aminoadipoyl)-L-cysteingyl-D-allylgycine into penam, homoceph-3-em, hydroxycepham, and hydroxyhomocepham type products; these have been isolated and their structures established.
J. E. Baldwin, R. M. Adlington, A. E. Derome, H. Ting and N. J. Turner, J. Chem. Soc., Chem. Commun., 1984, 1211 DOI: 10.1039/C39840001211
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