The norbornadienone acetals (1) with CO2Me, CONMe2, or CHO substituents at C-2 undergo rearrangement via formal 1,3-shift to norcaradienes under very mild conditions; strong donor-acceptor acceleration of either 1,3-sigmatropic rearrangement of C–C bond homolysis is indicated.
C. Bleasdale and D. W. Jones, J. Chem. Soc., Chem. Commun., 1984, 1200 DOI: 10.1039/C39840001200
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