Issue 17, 1984

[3]-, [4]-, and [5]-Pericyclyne: through-bond vs. through-space interactions

Abstract

MNDO calculations for [3]-, [4]-, and [5]-pericyclyne indicate that interactions between triple bonds are hyperconjugative in the π system and homoconjugative in the σ system and that [3]pericyclyne may be interconverted with a valence tautomer, tricyclopropabenzene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1188-1191

[3]-, [4]-, and [5]-Pericyclyne: through-bond vs. through-space interactions

M. J. S. Dewar and M. K. Holloway, J. Chem. Soc., Chem. Commun., 1984, 1188 DOI: 10.1039/C39840001188

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