The product of the reaction between p-tolyl azide and MoCl4(thf)2(thf = tetrahydrofuran) is shown to be the organoimido MoVI complex Mo(Ntolyl)Cl4(thf), and its molecular structure is described; in the presence of bipyridine or tertiary phosphine ligands, the title complex is readily reduced to yield organoimido MoV complexes Mo(Ntolyl)Cl3L2(L = PPh3, PPh2Et; L2= bipy, Ph2PC2H4PPh2).
C. Y. Chou, J. C. Huffman and E. A. Maatta, J. Chem. Soc., Chem. Commun., 1984, 1184 DOI: 10.1039/C39840001184
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