The oxidative addition of the P–H bond of (OC)5M(PPh2H)(M = Cr, Mo, W) to zerovalent platinum complexes initially forms heterobimetallic µ-phosphido terminal hydrido complexes which readily rearrange via bridging carbonyl and platinum–terminal carbonyl intermediates to give the µ-phosphido-µ-hydrido complexes (OC)4M(µ-PPh2)(µ-H)Pt(PR3)2.
J. Powell, M. R. Gregg and J. F. Sawyer, J. Chem. Soc., Chem. Commun., 1984, 1149 DOI: 10.1039/C39840001149
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