Thiophene S,N-ylides readily react with electron-rich dienophiles yielding adducts formed by the efficient extrusion of acyl- and sulphonyl-thionitroso-compounds, themselves readily trapped by Diels–Alder or ene reactions; similar but slower cycloadditions occur with the analogous S,C-ylides, a potential source of thiocarbonyl derivatives.
O. Meth-Cohn and G. van Vuuren, J. Chem. Soc., Chem. Commun., 1984, 1144 DOI: 10.1039/C39840001144
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...