Hydrogenation of the double bond at C(5) of diester (12) occurs exclusively from the si-si face provided that a bulky substituent is present at C(3) in cis relationship to the olefinic side chain.
M. Georges, T. F. Tam and B. Fraser-Reid, J. Chem. Soc., Chem. Commun., 1984, 1122 DOI: 10.1039/C39840001122
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