Reaction of the neutral hexaosmium cluster Os6(CO)18 with excess of pyridine (py) gives the pentanuclear dianion [Os5(CO)15]2– together with small amounts of a neutral hexanuclear cluster Os6(CO)17(py)2(1); X-ray analysis shows that (1) exhibits an unusual type of metal–carbonyl linkage.
B. F. G. Johnson, J. Lewis, M. McPartlin, M. Pearsall and A. Sironi, J. Chem. Soc., Chem. Commun., 1984, 1089 DOI: 10.1039/C39840001089
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