The substitution of MeOH in CoIII(protoporphyrin IX dimethyl ester)(MeO)(MeOH) by pyridine (py), 4Me-py, or 4CN-py in methanol is a D-type process with a limiting rate of 57.8 s–1 for all three ligands at 25 °C; the subsequent substitution of MeO– proceeds via the complex conjugate acid, also in a dissociative manner.
Z. Dokuzović, D. Pavlović, S. Ašperger and I. Murati, J. Chem. Soc., Chem. Commun., 1984, 1060 DOI: 10.1039/C39840001060
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