N-Silyl-protected primary aminomethyl sulphides and aminomethylphosphonates can be synthesised by the Lewis acid-catalysed reactions of silyl sulphides and silyl phosphites with N,N-bis(trimethylsilyl)methoxymethylamine.
T. Morimoto, M. Aono and M. Sekiya, J. Chem. Soc., Chem. Commun., 1984, 1055 DOI: 10.1039/C39840001055
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