The ability of cyclopentadienone to act as the diene counterpart in Diels–Alder reactions was demonstrated through the isolation of the cycloadduct with ethyl acrylate, which was utilized as the starting point for an expeditious synthesis of (±)-sarkomycin.
P. G. Baraldi, A. Barco, S. Benetti, G. P. Pollini, E. Polo and D. Simoni, J. Chem. Soc., Chem. Commun., 1984, 1049 DOI: 10.1039/C39840001049
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