2,2′-Bipyridyl and 1,10-phenanthroline can be diffused between the layers of pre-swelled α-Zr(HPO4)2·2H2O to give the materials α-Zr(HPO4)2[bipy]0.25·1.5H2O and α-Zr(HPO4)2[phen]0.5·2H2O; metal ions co-ordinate preferentially ot the stage I dispersed ligand with in situ formation of complex pillars.
C. Ferragina, M. Massucci, A. La Ginestra, P. Patrono and A. A. G. Tomlinson, J. Chem. Soc., Chem. Commun., 1984, 1024 DOI: 10.1039/C39840001024
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