when (E)-1-trimethylsilycyclo-octene (4) is treated with bromine in dichloromethane solution at –78 °C and the products are allowed to warm up to room temperature, (Z)-1-brimocyclo-oct-4-ene (5) is obtaine and can be isolated in ca. 70% yield.
D. Dhanak, C. B. Reese and D. E. Williams, J. Chem. Soc., Chem. Commun., 1984, 988 DOI: 10.1039/C39840000988
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