Issue 15, 1984

Fast time-resolved infrared spectroscopy of organometallic intermediates; detection of [(η5-C5H5)Fe(CO)2] and [(η5-C5H5)Fe(µ-CO)3Fe(η5-C5H5)] in room-temperature solution

Abstract

A line-tunable CO laser has been use as a fast (1 µs) i.r. monitor to obtain spectra (2012–1710 cm–1) and lifetimes of [CpFe(CO)2](Cp =η5-C5H5) and [CpFe(µ-CO)3FeCp], formed during u.v.–visible flash photolysis of [CpFe(CO)2]2 in cyclohexane solution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 972-974

Fast time-resolved infrared spectroscopy of organometallic intermediates; detection of [(η5-C5H5)Fe(CO)2] and [(η5-C5H5)Fe(µ-CO)3Fe(η5-C5H5)] in room-temperature solution

B. D. Moore, M. B. Simpson, M. Poliakoff and J. J. Turner, J. Chem. Soc., Chem. Commun., 1984, 972 DOI: 10.1039/C39840000972

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