Issue 15, 1984

E.s.r. evidence for the multiplicity of side-chain oxidation pathways in the acid-catalysed decomposition of substituted hydroxycyclohexadienyl radicals

Abstract

Addition of ˙OH to the aromatic rigns of 3-phenylpropanoic acid and 3-phenylpropanol is followed at low pH by two competing processes, oxidation at the side-chain terminus and loss of a benzylic hydrogen atom, in both of which radical-cations are believed to mediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 966-967

E.s.r. evidence for the multiplicity of side-chain oxidation pathways in the acid-catalysed decomposition of substituted hydroxycyclohexadienyl radicals

M. J. Davies, B. C. Gilbert, C. W. McCleland, C. B. Thomas and J. Young, J. Chem. Soc., Chem. Commun., 1984, 966 DOI: 10.1039/C39840000966

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