Diastereoisomeric tricyclo[6.3.1.01,6]dodecane derivatives (3) and (4), which correspond to the B/C/D ring systems of aphidicolane and stemodane diterpenes, were selectively prepared from the common spirodienone (5) by means of facile regioselective C–C bond formation mediated by the neighbouring hydroxy group participation.
C. Iwata, T. Morie, N. Maezaki, H. Shimamura, T. Tanaka and T. Imanishi, J. Chem. Soc., Chem. Commun., 1984, 930 DOI: 10.1039/C39840000930
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