Issue 14, 1984

An efficient thermal route to arenesulphenylnitrenes

Abstract

Arenesulphenylnitrenes are generated efficiently from sulphenamides, (1), on heating at ca. 80–120 °C and are trapped by alkenes as the corresponding aziridens in quantitative yield; this approach is shown to be more efficient and more widely applicable than the oxidation of arenesulphenamides but both reactions appear to reactions appear to involve the same nitrene intermediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 919-920

An efficient thermal route to arenesulphenylnitrenes

R. S. Atkinson, M. Lee and J. R. Malpass, J. Chem. Soc., Chem. Commun., 1984, 919 DOI: 10.1039/C39840000919

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