Arenesulphenylnitrenes are generated efficiently from sulphenamides, (1), on heating at ca. 80–120 °C and are trapped by alkenes as the corresponding aziridens in quantitative yield; this approach is shown to be more efficient and more widely applicable than the oxidation of arenesulphenamides but both reactions appear to reactions appear to involve the same nitrene intermediate.
R. S. Atkinson, M. Lee and J. R. Malpass, J. Chem. Soc., Chem. Commun., 1984, 919 DOI: 10.1039/C39840000919
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