The binuclear rhodium complex Rh22+(µ-P—P)2(MeOH)4H4, (2), P—P = 2,5-bis(diphenylphosphino)furan, is inferior to monoclear models in hydrogen transfer to 3,3-dimethylbut-1-ene; related mono-and di-nuclear iridium complexes exhibit contrasting chemistry.
J. M. Brown, L. R. Canning and A. R. Lucy, J. Chem. Soc., Chem. Commun., 1984, 915 DOI: 10.1039/C39840000915
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