The otherwise unstable CuIII complexed with tetra-aza macrocycles (1)–(3) are stabilized in strongly acidic solutions; the CuIII complex with the diene macrocycle (1) shows a grater stability (in 10 M HClO4)than the corresponding NiIII complex, an inversion of the normally observed trend.
C. B. Castellani, L. Fabbrizzi, M. Licchelli, A. Perotti and A. Poggi, J. Chem. Soc., Chem. Commun., 1984, 806 DOI: 10.1039/C39840000806
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