Issue 12, 1984

Alkyl compounds of diruthenium(III) and diosmium(III). X-Ray crystal structure of the first ruthenium peralkyl, hexakis(neopentyl)diruthenium(III)

Abstract

The interaction of RMgCl, R [double bond, length as m-dash] CH2SiMe3, CH2But with Ru2(C2CM)4Cl or Os2(O2CMe)4Cl2 leads to the compounds M2R6, M = Ru M2(µ-O2CMe)2R4 M [double bond, length as m-dash] Ru, Os; the structure of Ru2(CH2But)6 has been determined by an X-ray crystallographic analysis.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 799-800

Alkyl compounds of diruthenium(III) and diosmium(III). X-Ray crystal structure of the first ruthenium peralkyl, hexakis(neopentyl)diruthenium(III)

R. P. Tooze, M. Motevalli, M. B. Hursthouse and G. Wilkinsion, J. Chem. Soc., Chem. Commun., 1984, 799 DOI: 10.1039/C39840000799

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