Time-resolved i.r. spectroscopy is used to show that Mn(CO)5 and CO-bridged Mn2(CO)9 are the primary photoproducts of Mn2(CO)10 in hydrocarbon silution; 2Mn(CO)5→ Mn2(CO)10 and Mn2(CO)9+ CO → Mn2(CO)10 are established as the recombination processes.
S. P. Church, H. Hermann, F. Grevels and K. Schaffner, J. Chem. Soc., Chem. Commun., 1984, 785 DOI: 10.1039/C39840000785
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