In aqueous or alcoholic hydrochloric acid the 14α-hydroxy-ketone (1) undergoes epimerization and dehydration to give the 14β-hydroxy-ketone (2) and the 14β-alkoxy-15-ketones (3)–(5), together with the rearranged 17-alkoxy-16-en-15-ones (8) and (9).
A. B. Turner, J. Chem. Soc., Chem. Commun., 1984, 771 DOI: 10.1039/C39840000771
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