Issue 11, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

The structural isomers of {[ph(2-pyridyl)NLi]·[O[double bond, length as m-dash]P(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

Donald Barr,   William Clegg,   Robert E. Mulvey  and  Ronald Snaith  

Abstract

An X-ray crystallographic study of the title compound, (1), shows it to consist of two structural isomers, one, (1A), with a planar (LiN)2 ring structure provided by µ-amido ligands, but the other,(1B), with an (LiO)2 ring due to previously unobserved bridging by the oxygen of formally neutral ligand.

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Article information

DOI
https://doi.org/10.1039/C39840000700
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 700-701

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The structural isomers of {[ph(2-pyridyl)NLi]·[O[double bond, length as m-dash]P(NMe2)3]}2: dimeric species with alternative central (LiN)2 and (LiO)2 rings, the latter involving unprecedented neutral bridging oxygen ligands

D. Barr, W. Clegg, R. E. Mulvey and R. Snaith, J. Chem. Soc., Chem. Commun., 1984, 700 DOI: 10.1039/C39840000700

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