SCHEDULED MAINTENANCE
The exothermic addition in the gas phase of a small radical to a heteroatom attached to a formal carbonium ion centre involves an energy barrier whereas addition to the carbonium ion centre little or none.
P. C. Burgers, J. L. Holmes and J. K. Terlouw, J. Chem. Soc., Chem. Commun., 1984, 642 DOI: 10.1039/C39840000642
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